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姓 名: |
張雪 |
性 別: |
女 |
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職 稱: |
副研究員 |
學(xué) 歷: |
博士研究生 |
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電 話: |
021-54925154 |
傳 真: |
021-64166128 |
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電子郵件: |
xzhang@sioc.ac.cn |
個人主頁: |
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通訊地址: |
上海市零陵路345號 200032 |
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| 簡歷: |
教育背景: 2002年9月至2007年7月:中科院上海有機(jī)所金屬有機(jī)重點(diǎn)實(shí)驗室攻讀博士學(xué)位,專業(yè)為理論有機(jī)化學(xué),導(dǎo)師為丁奎嶺研究員 1998年9月至2002年7月:南開大學(xué)化學(xué)學(xué)院獲得學(xué)士學(xué)位 工作經(jīng)歷: 2011年3月至今:中科院上海有機(jī)化學(xué)研究所金屬有機(jī)化學(xué)國家重點(diǎn)實(shí)驗室麻生明組副研究員 2009年1月2011年2月:美國北德克薩斯大學(xué)(University of North Texas)Professor Weston T. Borden 研究組從事博士后研究 2007年7月至2008年12月:中科院上海有機(jī)所金屬有機(jī)重點(diǎn)實(shí)驗室丁奎嶺課題組,助理研究員 |
| 研究方向: |
運(yùn)用電子結(jié)構(gòu)理論研究不同類型分子體系的化學(xué)反應(yīng)機(jī)理 |
| 代表論著: |
1.Xue Zhang, Ayan Datta, David A. Hrovat, and Weston Thatcher Borden*, “Calculations Predict Large Inverse Kinetic Isotope Effects on Tunneling by Carbon in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperatures”, J. Am. Chem. Soc. 2009, 131, 16002-16003. 2.Xue Zhang, David A. Hrovat, and Weston Thatcher Borden*, “Calculations Predict That Carbon Tunneling Allows the Degenerate Cope Rearrangement of Semibullvalene to Occur Rapidly at Cryogenic Temperatures”, Org. Lett. 2010, 12, 2798-2801. 3.Xue Zhang, Srikanth Kandala, Li Yang, William H. Watson, Xiaoping Wang, David A. Hrovat, Weston Thatcher Borden,* and Michael G. Richmond*, “Experimental and Computational Studies of the Isomerization Reactions of Bidentate Phospine Ligands in Triosmium Clusters: Kinetics of the Rearrangements from Bridged to Chelated Isomers and X-ray Structures of the Clusters Os3(CO)10(dppbz), 1,1-Os3(CO)10(dppbzF4), HOs3(CO)9[μ-1,2-PhP (C6H4-η1)C6H4PPh2], and HOs3(CO)9[μ-1,2-PhP(C6H4-η1)C6F4PPh2]”, Organometallics 2011, 30, 1253–1268. 4.Xue Zhang, David A. Hrovat, Ayan Datta and Weston Thatcher Borden*, “Effects of Geminal Methyl Groups on the Tunnelling Rates in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperature”, Organic & Biomolecular Chemistry ASAP. 5.Xue Zhang, Haifeng Du, Zheng Wang, Yun-Dong Wu,* and Kuiling Ding*, “Experimental and Theoretical Studies on the Hydrogen-Bond-Promoted Enantioselective Hetero-Diels-Alder Reaction of Danishefsky’s Diene with Benzaldehyde”, J. Org. Chem. 2006, 71, 2862-2869. 6.Ollie M. Gonzalez-James, Xue Zhang, Ayan Datta, David A. Hrovat, Weston Thatcher Borden*, and Daniel A. Singleton*, “Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular 12C/13C Kinetic Isotope Effects”, J. Am. Chem. Soc. 2010, 132, 12548-12549. 7.Liu, Y.; Sandoval, C. A.; Yamaguchi, Y.; Zhang, X.; Wang, Z.; Kato, K.; Ding, K*., “Hydrogen Bonding Makes a Difference in the Rhodium-Catalyzed Enantioselective Hydrogenation Using Monodentate Phosphoramidites”, J. Am. Chem. Soc., 2006; 128, 14212-14213. 8.Qing Jing, Xue Zhang, Jie Sun, Kuiling Ding*, “Bulky Achiral Triarylphosphines Mimic BINAP in Ru(II)-Catalyzed Asymmetric Hydrogenation of Ketones”, Adv. Synth. Catal. 2005, 347, 1193–1197. 9.Haifeng Du, Xue Zhang, Zheng Wang, and Kuiling Ding*, “One catalyst for two distinct reactions: sequential asymmetric hetero Diels-Alder reaction and diethylzinc”, Tetrahedron, 2005, 40, 9465-9477. 10.Wen, YQ; Song, YL; Zhao, DB; Ding, KL; Bian, J; Zhang, X; Wang, JX; Liu, Y; Jiang, L; Zhu, DB, “Highly regio- and enantioselective thermal [2+2] cycloaddition of coumarin in a crystalline inclusion complex under high vacuum”, Chem. Commun. 2005, 21, 2732-2734. 11.Yu Yuan, Xue Zhang, and Kuiling Ding*, “Quasi solvent-free enantioselective carbonyl-ene reaction with extremely low catalyst loading”, Angew. Chem. Int. Ed. 2003, 42, 5478 –5480. |
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