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姓 名: |
劉國(guó)生 |
性 別: |
男 |
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職 稱: |
研究員 |
學(xué) 歷: |
研究生 |
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電 話: |
021-54925346 |
傳 真: |
021-64166128 |
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電子郵件: |
gliu@mail.sioc.ac.cn |
個(gè)人主頁(yè): |
http://guoshengliu.sioc.ac.cn |
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通訊地址: |
上海市零陵路345號(hào) 200032 |
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| 簡(jiǎn)歷: |
1991,9-1995,7南京理工大學(xué)化工學(xué)院,獲工學(xué)學(xué)士;
1996,9-1999,8中科院大連化學(xué)物理研究所,獲理學(xué)碩士;
1999,9-2002,8中科院上海有機(jī)化學(xué)研究所,獲理學(xué)博士;
2003,3-2005,7美國(guó)Lehigh大學(xué),博士后;
2005,8-2007,7美國(guó)威斯康辛大學(xué)麥迪遜分?;瘜W(xué)系,研究助理;
2007,7-中科院上海有機(jī)所研究員。 |
| 研究方向: |
| 本課題組的研究集中在有機(jī)化學(xué),金屬催化和材料化學(xué)的前沿交叉區(qū)域,主要基于C-M鍵的基元反應(yīng),通過(guò)設(shè)計(jì)和合成一些新型的金屬催化劑來(lái)實(shí)現(xiàn)有機(jī)分子的高選擇性轉(zhuǎn)化,并對(duì)反應(yīng)機(jī)理的進(jìn)行研究,從而能夠更多的了解這些金屬催化的反應(yīng),對(duì)金屬的基元反應(yīng)更多的認(rèn)識(shí)。 |
| 代表論著: |
- Wu, Liang; Qiu, Shuifa; Liu, Guosheng,* “Br?nsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes:Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.” Org. Lett. 2009, 11, 2707.
- Qiu, Shuifa; Wei, Yunyang; Liu, Guosheng;* “Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation.” Chem. Eur. J. 2009, 15, 2751.
- Liu, Guosheng;* Yin, Guoyin; Wu, Liang; “Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: effic- ient synthesis of linear allylamine derivatives.” Angew. Chem. Int. Ed. 2008, 47, 4733.
- Yin, Guoyin; Liu, Guosheng;* “Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant.” Angew. Chem. Int. Ed. 2008, 47, 5442.
- Chai, Jianfang; Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li;* Macromolecules 2008, 41, 8980.
- Liu, Guosheng; Stahl, Shannon. S;* “Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions.” J. Am. Chem. Soc. 2007, 129, 6328-6335.
- Liu, Guosheng; Stahl, Shannon. S;* “Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN2 C-O Bond Formation”, J. Am. Chem. Soc. 2006, 128, 7179-7181.
- Liu, Guosheng; Jia, Li;* “Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran”, Angw. Chem. Int. Ed. 2006, 45, 129.
- Liu, Guosheng; Jia, Li;* “Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s”, J. Am. Chem. Soc. 2004, 126, 14716.
- Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Coupling of Allenoic Acids and a,b-Unsaturated Carbonyl Compounds through Tandem Intramolecular oxypalladation and Conjugate Addition Reactions”, Tetrahedron Lett. 2003, 44, 127.
- Lei, Aiwen; Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Highly Regio- and Diastereoselective Cyclization of Difunctional Allylic N-Tosylcarbamates. A Convenient Synthesis of Optically Active 4-Vinyl-2-oxazolidinones and Total Synthesis of 1,4-Dideoxy-1,4-imino- L-xylitol”, J. Org. Chem. 2002, 67, 974.
- Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Coupling Reactions of Intramolecular Carbopalladation of Alkyne with Allylic Compounds”, Tetrahedron Lett. 2002, 43, 6791.
- Liu, Guosheng; Lu, Xiyan;* “Palladium(II)-Catalyzed Tandem Reaction of Intramolecular Aminopalladation of Allenyl N-Tosylcarbamates and Conjugate Addition”, Org. Lett. 2001, 3, 3879.
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