
2007-2012 中國科學(xué)院上海有機化學(xué)研究所博士。導(dǎo)師:游書力研究員和李玉學(xué)研究員
2003-2007 上海交通大學(xué)化學(xué)化工學(xué)院學(xué)士。導(dǎo)師:舒謀海教授
物理有機化學(xué)、手性合成
上海市自然科學(xué)獎一等獎(排名第三,2016年)
國家自然科學(xué)獎二等獎(排名第三,2017年)
中國科學(xué)院青年創(chuàng)新促進(jìn)會會員(2017年)
上海市青年科技啟明星(2018年)
上海市青年拔尖人才(2020年)
中國科學(xué)院青年創(chuàng)新促進(jìn)會優(yōu)秀會員(2021年)
1. Zheng, Y.; Zhang, W.-Y.; Gu, Q.;?Zheng, C.*; You, S.-L.* Cobalt(III)-Catalyzed Asymmetric Ring-Opening of 7-Oxabenzonorbornadienes via Indole C–H Functionalization.?Nat. Commun.?2023,?14, 1094.
2. Liu, C.-X.; Xie, P.-P.; Zhao, F.; Wang, Q.; Feng, Z.; Wang, H.;?Zheng, C.*; You, S.-L.*?Explicit Mechanism of Rh(I)-Catalyzed Asymmetric C–H Arylation and Facile Synthesis of Planar Chiral Ferrocenophanes.?J. Am. Chem. Soc.?2023,?145, 4765-4773.
3. Zhang, W.-W.; Wang, Q.; Zhang, S.-Z.;?Zheng, C.*; You, S.-L.* Rh-Catalyzed Asymmetric Satoh–Miura-type Reactions for Building-up Axial Chirality: Counteranion Directed Switch of Reaction Pathways.?Angew. Chem. Int. Ed.?2023,?62, e202214460.
4. Jiang, R.; Zhao, Q.-R.;?Zheng, C.*; You, S.-L.* Structurally Defined?anti-π-Allyliridium Complexes Catalyze?Z-Retentive Asymmetric Allylic Alkylation of Oxindoles.?Nat. Catal.?2022,?5, 1089-1097.
5. Zhu, M.; Zhang, X.*;?Zheng, C.*; You, S.-L.*?Energy-Transfer-Enabled Dearomative Cycloaddition Reactions of Indoles/Pyrroles via Excited-State Aromatics.?Acc. Chem. Res.?2022,?55, 2510-2525.
6. Liu, Y.-Z.; Song, H.;?Zheng, C.*; You, S.-L.*?Cascade Asymmetric Dearomative?Cyclization Reactions via Transition-metal-catalysis.?Nat. Synth.?2022,?1, 203-216.
7. Wang, Q.; Nie, Y.-H.; Liu, C.-X.; Zheng, W.-W.; Wu, Z.-J.; Gu, Q.;?Zheng, C.*; You, S.-L.* Rhodium(III)-Catalyzed Enantioselective C–H Activation/Annulation of Ferrocenecarboxamides with Internal Alkynes.?ACS Catal.?2022,?12, 3083-3093.
8. Zhu, M.;?Zheng, C.*?post-Spin Crossing Dynamics?Determines the Regioselectivity in Open-shell Singlet Biradical Recombination.?Org. Chem. Front.?2022,?9, 995-1003.
9. Zhu, M.; Huang, X.-L.; Sun, S.;?Zheng, C.*; You, S.-L.*?Visible-Light-Induced Dearomatization of Indoles/Pyrroles with Vinylcyclopropanes: Expedient Synthesis of Structurally Diverse Polycyclic Indolines/Pyrrolines.?J. Am. Chem. Soc.?2021,?143, 13441-13449.
10. Huang, L.; Xie, J.-H.; Cai, Y.;?Zheng, C.*; Hou, X.-L.; Dai, L.-X.; You, S.-L.* Enantioselective Synthesis of Polycyclic Pyrrole Derivatives by Iridium-Catalyzed Asymmetric Allylic Dearomatization and Ring-expansive Migration Reactions.?Chem. Commun.?2021,?57, 5390-5393.
11.?Zheng, C.; You, S.-L.*?Advances in Catalytic Asymmetric Dearomatization.?ACS Cent. Sci.?2021,?7, 432-444.
12. Jiang, R.; Ding, L.;?Zheng, C.; You, S.-L.* Iridium-Catalyzed?Z-Retentive Asymmetric Allylic Substitution Reactions.?Science?2021,?371, 380-386.
13. Zhu, M.; Xu, H.; Zhang, X.*;?Zheng, C.*; You, S.-L.*?Visible-light-induced Intramolecular Double Dearomative Cycloaddition of Arenes.?Angew. Chem. Int. Ed.?2021,?60, 7036-7040.
14. Liu, Q.-Q.;?Zheng, C.*; You, S.-L.* Silica Gel-promoted Synthesis of Multisubstituted Spiroindolenines from Tryptamines and?γ-Chloro-α,β-Unsaturated Ketones.?Tetrahedron?2021,?77, 131765.
15. Zhu, M.; Zhang, X.*;?Zheng, C.*; You, S.-L.*?Visible-light-induced Dearomatization via [2+2] Cycloaddition or 1,5-Hydrogen Atom Transfer: Divergent Reaction Pathways of Transient Diradicals.?ACS Catal.?2020,?10, 12618-12626.
16.?Zheng, C.*?Divergent Pathways and Dynamics Effects of Intramolecular Hydride Transfer Reactions Mediated by Cp*M(III) Complexes (M = Co, Rh, Ir).?Chin. J. Chem.?2020,?38, 1579-1584.
17. Zhu, M.; Huang, X.-L.; Xu, H.; Zhang, X.*;?Zheng, C.*; You, S.-L.*?Visible-Light-Mediated Synthesis of Cyclobutene-Fused Indolizidines and Related Structural Analogs.?CCS Chem.?2020,?2, 652-664.
18.?Zheng, C.*; You, S.-L.*?Exploring the Chemistry of Spiroindolenines by Mechanistically-Driven Reaction Development: Asymmetric Pictet–Spengler-type Reactions and Beyond.?Acc. Chem. Res.?2020,?53, 974-987.
19. Rossi-Ashton, J. A.; Clarke, A. K.; Donald, J. R.;?Zheng, C.*; Taylor, R. J. K.*; Unsworth, W. P.*; You, S.-L.*?Iridium Catalyzed Enantioselective Intermolecular Indole C2-Allylation.?Angew. Chem., Int. Ed.?2020, 59, 7598-7604.
20. Yang, P.#; Xu, R.-Q.#;?Zheng, C.*; You, S.-L.*?Pd-catalyzed Dearomatization of Indole Derivatives via Intermolecular Heck Reactions.?Chin. J. Chem.?2020,?38, 235-241.
21. Xia, Z.-L.; Xu-Xu, Q.-F.;?Zheng, C.*; You, S.-L.*?Chiral Phosphoric Acid-Catalyzed Asymmetric Dearomatization Reactions.?Chem. Soc. Rev.?2020,?49, 286-300.
22.?Zheng, C.*; You, S.-L.*?Catalytic Asymmetric Dearomatization Reaction Enabled Total Synthesis of Indole-based Natural Products.?Nat. Prod. Rep.?2019,?36, 1589-1605.
23. Zhu, M.;?Zheng, C.*; Zhang, X.*; You, S.-L.*?Synthesis of Cyclobutane-Fused Angular Tetracyclic Spiroindolines via Visible-Light-Promoted Intramolecular Dearomatization of Indole Derivatives.?J. Am. Chem. Soc.?2019,?141, 2636-2644.
24. Xia, Z.-L.;?Zheng, C.*; Liang, X.-W.; Cai, Y.; You, S.-L.*?Manipulation of Spiroindolenine Intermediates for Enantioselective Synthesis of 3-(Indol-3-yl)-pyrrolidines.?Angew. Chem., Int. Ed.?2019,?58, 1158-1162.
25. Yang, Z.-P.; Jiang, R.; Wu, Q.-F.; Huang, L.;?Zheng, C.*; You, S.-L.* Iridium-Catalyzed Intramolecular Asymmetric Allylic Dearomatization of Benzene Derivatives.?Angew. Chem., Int. Ed.?2018, 57, 16190-16193.
26.?Zheng, C.*; Xia, Z.-L.; You, S.-L.* Unified Mechanistic Understandings of Pictet–Spengler Reactions.?Chem?2018,?4, 1952-1966.
27. Yang, Z.-P.; Jiang, R.;?Zheng, C.*; You, S.-L.* Iridium-Catalyzed Intramolecular Asymmetric Allylic Alkylation of Hydroxyquinolines: Simultaneous Weakening of the Aromaticity of Two Consecutive Aromatic Rings.?J. Am. Chem. Soc.?2018,?140, 3114-3119.
28. Xia, Z.-L.;?Zheng, C.*; Wang, S.-G.; You, S.-L.* Catalytic Asymmetric Dearomatization of Indolyl Dihydropyridines through an Enamine Isomerization/Spirocyclization/Transfer Hydrogenation Sequence.Angew. Chem., Int. Ed.?2018,?57, 2653-2656.
29. Wang, Y.;?Zheng, C.*; You, S.-L.* Iridium-Catalyzed Asymmetric Allylic Dearomatization by a Desymmetrization Strategy.?Angew. Chem., Int. Ed.?2017,?56, 15093-15097.
30.?Zheng, C.; You, S.-L.*?Catalytic Asymmetric Dearomatization by Transition-Metal-Catalysis: A Method for Transformations of Aromatic Compounds.?Chem?2016,?1, 830-857.
31. Wu, Q.-F.;?Zheng, C.*; Zhuo, C.-X.; You, S.-L.* Highly Efficient Synthesis and Stereoselective Migration Reactions of Chiral Five-Membered Aza-Spiroindolenines: Scope and Mechanistic Understanding.?Chem. Sci.?2016,?7, 4453-4459.
32.?Zheng, C.*; Zheng, J.; You, S.-L.* A DFT Study on Rh-Catalyzed Asymmetric Dearomatization of 2-Naphthols Initiated with C–H Activation: A Re?ned Reaction Mechanism and Origins of Multiple Selectivity.?ACS Catal.?2016,?6, 262-271.
33.?Zheng, C.*; Zhuo, C.-X.; You, S.-L.* Mechanistic Insights into the Pd-Catalyzed Intermolecular Asymmetric Allylic Dearomatization of Multisubstituted Pyrroles: Understanding the Remarkable Regio- and Enantioselectivity.?J. Am. Chem. Soc.?2014,?136,?16251-16259.
34. Liu, H.;?Zheng, C.*; You, S.-L.* Fe(OTf)3?Catalyzed Annulation of 2,3-Disubstituted Indoles with Aziridines.?Chin. J. Chem.?2014,?32, 709-714.
35. Liu, H.;?Zheng, C.*; You, S.-L.* Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate.?J. Org. Chem.?2014,?79, 1047-1054.
36.?Zheng, C.; You, S.-L.* Recent Development of Direct Asymmetric Functionalization of Inert C–H Bonds.?RSC Adv.2014,?4, 6173-6214.
37.?Zheng, C.*; Wu, Q.-F.; You, S.-L.* A Combined Theoretical and Experimental Investigation into the Highly Stereoselective Migration of Spiroindolenines.?J. Org. Chem.?2013,?78, 4357-4365.

