1993/9 - 1997/6，四川大學(xué)，化學(xué)，學(xué)士，導(dǎo)師：陳耀強 教授
1997/9 - 2000/6，蘭州大學(xué)，化學(xué)，碩士，導(dǎo)師：曾正志 教授
2001/9 - 2007/6，加拿大新布倫瑞克大學(xué)，化學(xué)，博士，導(dǎo)師：Jack Passmore 教授
2007/11 - 2010/10，加州大學(xué)戴維斯分校，化學(xué)，博士后，導(dǎo)師：Philip P. Power 教授
2010/11 - 2012/3，南京大學(xué)，化學(xué)化工學(xué)院，配位化學(xué)國家重點實驗室，副教授
2012/4 - 2023/2，南京大學(xué)，化學(xué)化工學(xué)院，配位化學(xué)國家重點實驗室，教授
2022/7 - 至今，中國科學(xué)院上海有機(jī)化學(xué)研究所，金屬有機(jī)化學(xué)國家重點實驗室，研究員
主族元素化學(xué)，自由基化學(xué)，金屬有機(jī)化學(xué)，小分子活化
50.?L. He, S. Kong, W. Jia, X. Wang,* A Constraining and Redox-Active Aluminum Species with Diverse Reactivity,?Angew. Chem. Int. Ed.?2025, DOI: 10.1002/anie.202524691.
49.?J. Huang, L. He, R. Pei, X. Wang,* Reversible Interconversion between a Carbon-Carbon Double Bond and Diradical Beyond External Stimulus.?J. Am. Chem. Soc.?2025，ASAP,?https://pubs.acs.org/doi/10.1021/jacs.5c18532.
48. ?Y. Zhao, W. Wang,* L. Zhang, T. Wang, L. He, Q. Sun, Y. Zhao, X. Wang.* An Olefin Radical Based Thiele′s Hydrocarbon Derivative and Macrocyclic Tetraradical.?Angew. Chem. Int. Ed.?2025, e202500943.
47.?T. Wang, S. Tang, X. Dong, Y. Zhao, Q. Sun, S. Kong, Y. Zhao, X. Wang*, Rational Design of Crystalline and Enantiomerically Pure Helicenes with Open-Shell Singlet Ground States.?Angew. Chem. Int. Ed.?2024,?e202415331
46. Y. Zhao, Y. Zhang, T. Wang, R. Pei, Y. Zhao, X. Xue,* X. Wang,*?A Thermally Populated Germylene-Based Donor-Acceptor Diradical,?Angew. Chem. Int. Ed.?2024, e202411180.
45. R. Pei, W. Chang, L. He, T. Wang, Y. Zhao, Y. Liang,* X. Wang,* Main-Group Compounds Selectively Activate Natural Gas Alkanes under Room Temperature and Atmospheric Pressure,?Nat. Commun.?2024,15, 7943.
44. S. Kong,?L. Yang,?Q. Sun,T. Wang,?W. Wang,?Y. Zhao,?R. Pei, Y. Zhao, H. Cui,* X. Gu,* X. Wang,* Metal-Free Catalytic Formation of a Donor-Acceptor-Donor Molecule and Its Lewis Acid- Adduct Singlet Diradical with High-Efficient NIR-II Photothermal Conversion.?Angew. Chem. Int. Ed.?2024,?e202400913.
43.?S. Tan, X. Wang.* Spin Frustration in Organic Radicals.?Angew. Chem. Int. Ed.?2024,?
e202310147.
42. R. Pei, L. He, Y. Zhao, X. Wang.* The Dynamic Lewis Acid-Carbene Hybrid: Pushing the Electrophilicity of Carbenes to the Limit.?J. Am. Chem. Soc. 2023,?145, 21733.
41.??X. Dong, Q.?Luo, Y. Zhao, T. Wang, Q.?Sun, R. Pei, Y. Zhao, Y.?Zheng* and?X. Wang*. A Dynamic Triradical：Synthesis, Crystal Structure and Spin Frustration.?J. Am. Chem.?Soc.?2023,?145, 17292.
40.??M. Liu, X. Yang, Q. Sun, T. Wang, R. Pei, X. Yang, Y. Zhao, L. Zhao,* G. Frenking,* X. Wang,*?Lewis Acid-Mediated Radical Stabilization and Dynamic Covalent Bonding: Tunable, Reversible and Photocontrollable.?Angew. Chem. Int. Ed.?2023, ?e202300068.???
39.??W.?Wang,?X.?Ma,?M.?Liu,?S.?Tang, X.?Ding, Y.?Zhao, Y.?Tan,*?M.?Kertesz,*?X.?Wang,*?A Triply Negatively Charged?Nanographene Bilayer with Spin Frustration. Angew. Chem. Int. Ed.?2023, e202217788.?
38.??J. Wang, H. Cui, H. Ruan, Y. Zhao, Y. Zhao, L. Zhang,*?X. Wang,* The Lewis Acid-Induced Formation of a Stable Diradical with an Intra Molecular Ion Pairing State.?J. Am. Chem. Soc.?2022,?144,?18,?7978-7982.?
37.??Z. Feng, S. Tang, Y. Su,?X. Wang,* Recent Advances in Stable Main Group Element Radicals: Preparation and Characterization.?Chem. Soc. Rev.?2022,?51, 5930-5973.??
36.??W.?Yang, L. Zhang,?D. Xiao,?R. Feng,?W. Wang, Y. Zhao, L. Zhao,* G. Frenking,*?X. Wang,*?A Diradical Based on Odd-Electron σ-Bonds.?Nat. Commun.?2020,?11:1-8.?DOI: 1038/s41467-020-17303-4. Highlighted in?Nat. Rev. Chem.?(Bonding Electrons Happy with Single Life.?Nat. Rev. Chem.?2020,?4, 438).?
35.??D.?Tuo,?C.?Chen,?H.?Ruan, Q.?Wang, Y.?Ao,?X.?Wang,*?D.?Wang,* Magnetic Multistability in an Anion Radical Pimer.?Angew. Chem. Int. Ed.?2020,?59, 14040-14043.?
34.??S.?Tang, L.?Zhang, H.?Ruan, Y.?Zhao,?X.?Wang,*?A Magnetically Robust Triplet Ground State Sulfur-?Hydrocarbon Diradical Dication.?J. Am. Chem. Soc.?2020,?142, 7340-7344.?
33.??C.?Chen,?H.?Ruan, Z.?Feng, Y.?Fang, Y.?Zhao, Y.?Su,*?X.?Wang,*?Crystalline Diradical Dianions of Azaacenes.?Angew. Chem. Int. Ed.?2020,?59, 11794-11799.?
32.??Z.?Feng,?Y.?Fang,?H.?Ruan, Y.?Zhao, G.?Tan,*?X.?Wang,*?Stable Radical Cation and Dication of an N-Heterocyclic Carbene Stabilized Digallene: Synthesis, Characterization and Reactivity，Angew. Chem. Int. Ed.?2020,?59, 6769-6774.?
31.??S.?Tang,?H.?Ruan, R.?Feng, Y.?Zhao, G.?Tan, L.?Zhang,*?X.?Wang*,?Tunable Reduction of 2,4,6-Tri(4-pyridyl)-1,3,5-Triazine: from Radical Anion to Diradical Dianion to Radical-Contained Metal-Organic Framework, Angew. Chem. Int. Ed.?2019,?58, 18224-18229.?
30.??M.?Mondal, L.?Zhang, Z.?Feng, S.?Tang, R.?Feng, Y.?Zhao, G.?Tan,*
H.?Ruan,*?X.?Wang*,?Tricoordinate Nontrigonal Pnictogen-Centered Radical Anions: Isolation, Characterization and Reactivity，Angew. Chem. Int. Ed.?2019,?58, 15829-15833.?
29.??R.?Feng, L.?Zhang, H.?Ruan, Y.?Zhao, G.?Tan* and?X.?Wang*,?A Main-Group Element Radical Based One-Dimensional Magnetic Chain,?Angew. Chem.?Int. Ed.?2019,?58, 6084-6088.?
28.??W. Wang, C. Chen, C. Shu, S. Rajca,?X. Wang,*?A. Rajca,*?S?= 1 Tetraazacyclophane Diradical Dication with Robust Stability: A Case of Low-Temperature One-Dimensional Antiferromagnetic Chain,?J. Am. Chem. Soc.?2018,?140, 7820-7826.?
27.??W. Wang, C. Xu, Y. Fang, Y. Zhao, J. Li,*?X. Wang,*?An Isolable Diphosphene Radical Cation Stabilized by Three-Center Three-Electron π-Bonding with Chromium: End-On versus Side-On Coordination,?Angew .Chem. Int. Ed.?2018,?57, 9563–9568.?
26.??T.?Li, H.?Wei, Y.?Fang, L.?Wang, S.?Chen, Z.?Zhang, Y.?Zhao, G.?Tan,*?X.?Wang,*?Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies,?Angew. Chem. Int. Ed.2017,?56, 632.?
25.??L.?Wang, L.?Zhang, Y.?Fang, J.?Li, C.?Chen, Y.?Zhao, Y.?Song, L.?Deng, G.?Tan,*?X.?Wang,*?P.?P. Power,*?Isolable Borane-Based Diradical and Triradical Fused by a Diamagnetic Transition Metal Ion,?J. Am. Chem. Soc.?2017,?139, 17723.?
24.??G.?Tan,?X.?Wang,*?Isolable Bis(triarylamine) Dications: Analogues of Thiele’s, Chichibabin’s, and Müller’s Hydrocarbons,?Acc. Chem. Res.?2017,?50, 1997.?
23.??W.?Wang, J.?Li, L.?Yin, Y.?Zhao, Z.?Ouyang,?X.?Wang,*?Z.?Wang,* Y.?Song,* P.?P. Power,*?Half-Sandwich Metal Carbonyl Complexes as Precursors to Functional Materials: From a Near-Infrared Absorbing Dye to a Single-Molecule Magnet,?J. Am. Chem. Soc.?2017,?139, 12069.?
22.??G.?Tan, J.?Li, Li Zhang, C.?Chen, Y.?Zhao,?X.?Wang,*?Y.?Song,* Y.?Zhang,* M.?Driess,*?The Charge Transfer Approach to Heavier Main-Group Element Radicals in Transition Metal Complexes,?Angew. Chem. Int. Ed.?2017,?56, 12741.?
21.??T. Li, G. Tan, D. Shao, J. Li, Z. Zhang, Y. Song, Y. Sui, S. Chen, Y. Fang,?X. Wang,*?Magnetic Bistability in a Discrete Organic Radical,?J. Am. Chem. Soc.?2016,?138, 10092-10095.?
20.??G. Tan, S. Li, S. Chen, Y. Sui, Y. Zhao,?X. Wang,*?Isolable Diphosphorus-Centered Radical Anion and Diradical Dianion.?J. Am. Chem. Soc.?2016,?138, 6735-6738.?
19.??X. Zheng, X. Wang, Z. Zhang, Y. Sui,?X. Wang,*?P. P. Power,* Access to Stable Metalloradicals with Unsupported and Isomeric Metal-Metal Hemi-Bonds,?Angew. Chem. Int. Ed.?2015,?54, 9084–9087 (VIP Paper).?
18.?Y. Su, X. Wang, Y. Li, Y. Song, Y. Sui,?X. Wang,*?Nitrogen Analogues of Thiele’s Hydrocarbon：Closed-Shell vs Open-Shell in the Ground State,?Angew. Chem. Int. Ed.?2015,?54, 1634–1637.?
17.??S. Zhang, X. Wang, Y. Sui,*?X. Wang,*?Odd-Electron Bonded Sulfur Radical Cations: X-ray Structural Evidence of a Sulfur-Sulfur Three-Electron σ–Bond,?J. Am. Chem. Soc.?2014,?136, 14666–14669. Highlighted by C&E News (“When Three Electrons Are Not a Crowd”, Oct. 27, 2014)?
16.??X. Pan, X. Wang, Y. Zhao, Y. Sui, and?X. Wang,*?A Crystalline Phosphaalkene Radical Anion,?J. Am. Chem. Soc.?2014,?136, 9834–9837.?
15.??S. Zhang, X. Wang, Y. Su, Y. Qiu, Z. Zhang, and?X. Wang,*?Isolation and Reversible Dimerization of a Selenium–Selenium Three–Electron σ–Bond,?Nat. Commun. 2014,?5, 4127.?
14.??Y. Su, X. Zheng, X. Wang, X. Zhang, Y. Sui, and?X. Wang,*?Two Stable Phosphorus-Containing Four-Membered Ring Radical Cations with Inverse Spin Density Distributions,?J. Am. Chem. Soc.?2014,?136, 6251–6254.?
13.??Y. Su, X. Wang, X. Zheng, Z. Zhang, Y. Song, Y. Sui, Y. Li, and?X. Wang,*?Tuning Ground States of Bis(triphenylamine)benzidine Dications by Substituent Effect: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State,?Angew. Chem. Int. Ed.?2014,?53, 2857–2861.?
12.??X. Zheng, X. Wang, Y. Qiu, Y. Li, C. Zhou, Y. Sui, Y. Li, J. Ma, and?X. Wang*, One-Electron Oxidation of an Organic Molecule by B(C6F5)3; Isolation and Structures of Stable Non-para-substituted Triarylamine Cation Radical and Bis(triarylamine) Dication Diradicaloid,?J. Am. Chem. Soc.?2013,?135, 14912–14915.?
11.??X. Pan, Y. Su, X. Chen, Y. Zhao, Y. Li, J. Zuo, and?X. Wang,*?Stable Tetraaryldiphosphine Radical Cation and Dication,?J. Am. Chem. Soc.?2013,?135, 5561–5564.?
10.??X. Pan, X. Chen, T. Li, Y. Li, and?X. Wang,*?Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations,?J. Am. Chem. Soc.?2013,?135, 3414–3417.?
9.??X. Chen, X. Wang, Z. Zhou, Y. Li, Y. Sui, J. Ma,?X. Wang,*?P. P. Power,* Reversible σ-Dimerizations of Persistent Organic Radical Cations,?Angew. Chem. Int. Ed.?2013,?52, 589–592.?
8.??X. Chen, X. Wang, Y. Sui,Y. Li, J. Ma,* J. Zuo and?X. Wang,*?Synthesis,Characterization and Structures of a Persistent Aniline Radical Cation,?Angew. Chem. Int. Ed.?2012,?51,11878–11881.?
7.??X. Wang,*?P. P. Power,* Structural Characterization, Infrared Spectroscopy and Theoretical Calculations for B(C6F5)3?Stabilized Benzene-Ammonia and Benzene-Water Complexes,?Angew. Chem. Int. Ed.?2011,?50, 10965–10968.?
獨立工作前：?
6.??X. Wang, Y. Peng, M. M. Olmstaead, H. Hope, P. P. Power*, A ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr'GeGeAr']+SbF6？?and [Ag2Ar'GeGe(F)Ar']+SbF6-?(Ar'=C6H3-2,6(C6H3-2,6-Pri2)2),?J. Am. Chem. Soc.?2010,?132, 13150 - 13151.?
5.??X. Wang, Y. Peng, Z. Zhu, J. C. Fettinger, P. P. Power*, J. Guo, S. Nagase. Synthesis and characterization of two of the three isomer models of a germanium substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond,?Angew. Chem. Int. Ed.?2010,?49, 4593 - 4597.?
4.??X. Wang, Y. Peng, J. C. Fettinger, M. Olmstead, P. P. Power*, An unsymmetric oxo/imido bridged germanium-centered singlet diradicaloid,?J. Am. Chem. Soc.?2009,?131, 14164 – 14165.?
3.??X. Wang, Z. Zhu, Y. Peng, H. Lei, J. C. Fettinger, P. P. Power*. Room-temperature reaction of carbon monoxide with a stable diarylgermylene,?J. Am. Chem. Soc., 2009,?131, 6912 - 6913.?
2.??T. S. Cameron (X-ray), J. Passmore* (Supervisor),?X. Wang. The Preparation and X-ray Crystal Structure of [(AgI2)n]MF6?(M=Sb, As): Diiodine Acting as a Donor in the Planar Polymeric [(AgI2)n]n+,?Angew Chem. Int. Ed.?2004,?43, 1995 – 1998.?(作者按姓氏第一個英文字母順序排列).?
Selected as a textbook example：Housecroft & Sharpe，Inorg. Chem. 3rd ed，Pearson，2006，p542.?
1.??A. Decken (X-ray), J. Passmore* (Supervisor),?X. Wang. Cyclic dimethylsiloxanes as pseudo crown ethers: Syntheses and characterization of Li(Me2SiO)5[Al{OC(CF3)3}4], Li(Me2SiO)6[Al{OC(CF3)3}4], and Li(Me2SiO)6[Al{OC(CF3)3Ph}4],?Angew. Chem. Int. Ed.?2006,?45, 2773 - 2777. (作者按姓氏第一個英文字母順序排列).?
Highlighted in C&E News (April 10, 2006, P54) and Angew Chem. Int. Ed. ( 2007, 46, 4610 - 4613).?
